Organic Chemistry

Chapter 11: Spectroscopy

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Infrared (IR) spectroscopy measures ____.

Molecular vibrations can be seen as ____.

To record an IR spectrum, i____e is measured.

The infrared light range runs from λ = ____.

The useful absorptions for infrared spectroscopy occur at wavelengths of ____ nm.

On an IR spectrum, we use an analog of ____ called wavenumber.

On an IR spectrum, we use an analog of frequency called ____.

The standard range on an IR spectrum corresponding to ____ nm is 4000 to 400 cm -1 .

The standard range on an IR spectrum corresponding to 2500 to 25,000 nm is ____ cm -1 .

When light of certain wavenumbers is absorbed, the molecules enter ____.

Six types of molecular vibrations that can occur are ____.

Frequency Equation: ____

Wavenumber Equation: ____

____ do not show up in IR spectra because they involve no net change in dipole movement.

For an absorption to be recorded, the vibration must result in a change in the ____.

Infrared spectroscopy detects change in ____.

Raman spectroscopy detects change in ____.

Molecules that do not experience a change in dipole moment are ____.

Absorption of this functional group, in C-H bond, would occur at ____ cm -1 .

____Absorption of this functional group, in C-H bond, would occur at 2800 ‒ 3000 cm -1 .

____Absorption of this functional group, in C-H bond, would occur at 3050 ‒ 3150 cm -1 .

Absorption of this functional group, in C-H bond, would occur at ____ cm -1 .

Absorption of this functional group, in C-C bond, would occur at ____ cm -1 .

____Absorption of this functional group, in C-C bond, would occur at 2100 ‒ 2200 cm -1 .

____Absorption of this functional group, in C-H bond, would occur at 3250 ‒ 3350 cm -1 .

Absorption of this functional group, in C-H bond, would occur at ____ cm -1 .

Absorption of this functional group, in a type of hydrogen bond, would occur at ____ cm -1 .

____Absorption of this functional group, in a type of hydrogen bond, would occur at 3100 ‒ 3600 cm -1 .

Absorption of this functional group, in a type of hydrogen bond, would occur at ____ cm -1 .

____Absorption of this functional group, in a type of hydrogen bond, would occur at 2800 ‒ 3200 cm -1 .

____Absorption of this functional group, in a type of carbon to something bond, would occur at 1700 ‒ 1750 cm -1 .

Absorption of this functional group, in a type of carbon to something bond, would occur at ____ cm -1 .

____Absorption of this functional group, in a type of carbon to something bond, would occur at 1000 ‒ 1200 cm -1 .

Absorption of this functional group, in a type of carbon to something bond, would occur at ____ cm -1 .

____Absorption of this functional group, in a type of C-C bond, would occur at 1620 ‒ 1680 cm -1 .

Absorption of this functional group, in a type of C-C bond, would occur at ____ cm -1 .

Absorption of this bond/functional group would occur at ____ cm -1 .

____Absorption of this bond/functional group would occur at 3250 ‒ 3500 cm -1 .

____Absorption of this bond/functional group would occur at 2220 ‒ 2260 cm -1 .

Absorption of this bond/functional group would occur at ____ cm -1 .

Absorption of this bond/functional group would occur at ____ cm -1 .

____Absorption of this bond/functional group would occur at 1700 ‒ 1750 cm -1 .

____Absorption of this bond/functional group would occur at 1700 ‒ 1750 cm -1 .

Absorption of this bond/functional group would occur at ____ cm -1 .

Absorption of this bond/functional group would occur at ____ cm -1 .

____Absorption of this bond/functional group would occur at 1735 ‒ 1750 cm -1 .

____Absorption of this functional group, in the C-C bond, would occur at 1500 ‒ 1600 cm -1 .

Absorption of this functional group, in the C-C bond, would occur at ____ cm -1 .

____Absorption of this functional group, in the C-H bond, would occur at 2900 ‒ 3100 cm -1 .

Absorption of this functional group, in the C-H bond, would occur at ____ cm -1 .

Absorption of this bond/functional group, in the C-H bond, would occur at ____ cm -1 .

____Absorption of this bond/functional group, in the C-H bond, would occur at 2700 ‒ 2900 cm -1 .

O-H bond gives a ____ peak around 3300 cm -1 .

____ bond gives a broad peak around 3300 cm -1 .

O-H bond gives a broad peak around ____ cm -1 .

____ bond gives a sharp peak around 3300 cm -1 .

N-H bond gives a ____ peak around 3300 cm -1 .

N-H bond gives a sharp peak around ____ cm -1 .

C=O bond gives a sharp peak around ____ cm -1 .

____ bond gives a sharp peak around 1750 cm -1 .

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