Organic Chemistry · Chapter 11: Spectroscopy

Question

The more conjugated the compound, the ____ the wavelength of maximum absorbance.

Answer

The more conjugated the compound, the lower the energy of the transition and the greater the wavelength of maximum absorbance.
The more conjugated the compound, the lower the energy of the transition and the greater the wavelength of maximum abso…
In Summary: UV and visible spectroscopy can be used to detect electronic excitations in conjugated molecules. With an increasing number of molecular orbitals, there is an increasing variety of possible transitions and hence number of absorption bands. The band of longest wavelength is typically associated with the movement of an electron from the highest occupied to the lowest unoccupied molecular orbital. Its energy decreases with increasing conjugation.

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