General Chemistry · 1EK: General Chemistry

Question

Elements in Groups ____ are expected to have nearly half-filled or nearly filled d subshells.

Answer

Elements in Groups 6 and 11 are expected to have nearly half-filled or nearly filled d subshells.
Elements in Groups 6 and 11 are expected to have nearly half-filled or nearly filled d subshells.
Note: It is also important to know that there are a few exceptions to the electron configuration rules in the transition metals. Half-filled and filled subshells offer greater stability. Elements in Groups 6 and 11 are expected to have nearly half-filled or nearly filled d subshells. Instead they borrow one electron from the highest s subshell so they end up with a half-filled s subshell and a half-filled or filled d subshell. This phenomenon is most likely to appear on the MCAT® with the elements Cr and Cu, which have only one electron in the 4s orbital. The electron configuration of Cr is [Ar] 4s1 3d5 and the electron configuration of Cu is [Ar] 4s1 3d10. Know these two notable exceptions in case they appear on the MCAT®.

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